It is a common heterocyclic compound, the ruthenium-catalysts compound, Dichlorotris(triphenylphosphino)ruthenium (II), cas is 15529-49-4 its synthesis route is as follows.,15529-49-4
General procedure: The same basic method, as described here for [RuCl(PPh3)2(LMe,H)]Cl, was followed for all the complexes in this study. Asuspension of [RuCl2(PPh3)3] (0.36 g, 0.4 mmol) and LMe,H (0.15 g,0.4 mmol) in dry dichloromethane (15 cm3) was stirred for 3 h atroom temperature. This yielded an orange precipitate, which wascollected by filtration. Alternatively, the products 3-6 were solublein the reaction mixture, and were precipitated from it by careful addition of diethyl ether. In either case, the resultant solids werewashed repeatedly with diethyl ether to remove excess PPh3, thendried in vacuo.
With the complex challenges of chemical substances, we look forward to future research findings about Dichlorotris(triphenylphosphino)ruthenium (II)
Reference£º
Article; Roberts, Thomas D.; Halcrow, Malcolm A.; Polyhedron; vol. 103; (2016); p. 79 – 86;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI