246047-72-3, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 246047-72-3, C46H65Cl2N2PRu. A document type is Article, introducing its new discovery.
Double C-H activation of an N-heterocyclic carbene ligand in a ruthenium olefin metathesis catalyst
(Chemical Equation Presented) Having a breakdown: Decomposition of the olefin metathesis catalyst [(biph)(PCy3)Cl2Ru=C(H)Ph] (biph = N,N?-diphenylbenzimidazol-2-ylidene, Cy = cyclohexyl) results in benzylidene insertion into an ortho C-H bond of an N-phenyl group of the biph ligand. The ruthenium center further inserts into another ortho C-H bond of the other N-phenyl ring to give a new Ru-C bond as a part of a five-membered metallacycle (see scheme).
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI