Archives for Chemistry Experiments of 301224-40-8

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Comprehensive study on olefin metathesis in PEG as an alternative solvent under microwave irradiation

Polyethylene glycols (PEGs) are non-toxic, biodegradable and sustainable organic solvents, which find a large application in the chemical and pharmaceutical industry. In this study, we present the ring-closing metathesis reaction (RCM) in PEG under microwave irradiation. Several benchmark substrates, yielding 5- to 6-membered rings featuring di- or tri-substituted olefins, were evaluated. This study demonstrated that PEGs are suitable solvent for olefin metathesis. However, depending on the substrate/catalyst couple, isomerization may occur.

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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI