A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article£¬once mentioned of 15746-57-3, name: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)
Synthesis and excited-state propertdies of a novel ruthenium nucleoside: 5-[Ru(bpy)2(4-m-4?-pa-bpy)]2+-2?-deoxyuridine
The synthesis and photophysical properties of a novel ruthenium-modified nucleoside are reported. The key synthetic step to 5-[Ru(bpy)2(4-m-4?-pa-bpy)]2+-2?-deoxyuridine involves the Pd(0)-catalyzed cross-coupling of a propargylamine-derivatized Ru(bpy)32+ and 3?,5?-dibenzoyloxy-2?-deoxy-5-iodouridine. The long-lived 3MLCT excited state (1300 ns) of 5-[Ru(bpy)2(4-m-4?-pa-bpy)]2+-2?-deoxyuridine has an emission maximum centered at 640 nm. Step-scan Fourier transform infrared (S2FTIR) time-resolved spectroscopy reveals the excited-state electron to be localized on the modified bipyridine with the excited-state dipole oriented toward the 2?-deoxyuridine.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In my other articles, you can also check out more blogs about 15746-57-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI