10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 10049-08-8, COA of Formula: Cl3Ru
Red and blue luminescent metallo-supramolecular coordination polymers assembled through pi-pi interactions
The use of pi-stacking interactions to control the aggregation of photo-active metal centres is explored through the design of bis(2,2?;6?,2?-terpyridyl) metal complexes functionalised with biphenyl ‘tails’. Aryl-aryl interactions control the aggregation of the metal complexes into polymetallic arrays in the solid state. Cobalt(n), ruthenium(n), nickel(n), copper(n), zinc(n) and cadmium(n) bis-ligand complexes and a mixed ligand ruthenium(n) complex have been structurally characterised. The solid-state structures are dependent on which units dominate the pi-stacking. For cobalt, ruthenium, nickel and copper, biphenylene-biphenylene interactions lead to linear rod-like arrays, while for the group 12 d10 ions zinc and cadmium, biphenylene-pyridyl interactions lead to two-dimensional sheets. The addition of the biphenylene tail has favourable effects on the photophysical-properties of the complexes which exhibit room temperature red (ruthenium) or blue (zinc and cadmium) luminescence, both in solution and the solid state. The Royal Society of Chemistry 2000.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.COA of Formula: Cl3Ru. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI