In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.COA of Formula: C20H16Cl2N4Ru
Ln2M complexes (M = Ru, Re) derived from a bismacrocyclic ligand containing a 4,4?-dimethyl-2,2?-bipyridyl bridging unit
Homodinuclear lanthanide complexes derived from a ligand featuring two DO3A chelating sites linked by a 4,4?-dimethyl-2,2?-bipyridyl spacer were prepared and characterized. The bipyridyl coordination site of 1 was used to introduce Ru(Bpy)2 and Re(CO)3Cl moieties, leading to the formation of heterometallic d-f2 complexes with general formulae [Ln2¡¤1¡¤Ru(Bpy)2]2+ (Ln = Nd, Eu, Tb, Yb and Lu) and [Ln2¡¤1¡¤Re(CO)3Cl] (Ln = Nd, Yb and Lu). The luminescence properties of the complexes were investigated by means of absorption spectroscopy and steady-state and time-resolved luminescence spectroscopy covering the visible and NIR regions. Both Ru and Re chromophores were shown to act as efficient sensitizers of the NIR emission of Yb and Nd in aqueous solutions. We also consider the unsaturated coordination spheres of the Ln cations in the Ln2¡¤1 complexes, which form ternary complexes with bidentate anions without showing particular synergistic effects for polyanionic species.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI