The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Safety of Dichloro(benzene)ruthenium(II) dimer
Extending the Chemistry of Hexamethylenetetramine in Ruthenium-Catalyzed Amine Oxidation
A very efficient, highly atom economical, and environmentally benign oxidation of primary and secondary amines using an in situ catalyst system generated from commercially available ruthenium(II) benzene dichloride dimer and hexamethylenetetramine has been demonstrated. Mechanistic studies revealed that hexamethylenetetramine acted as a source of hydride to generate the active ruthenium hydride catalyst and amine oxidation involves a dehydrogenative pathway. In comparison to reported catalyst systems for the dehydrogenative oxidation of amines, this synthetic protocol makes use of a simple ruthenium precursor and a cheaper additive; it is very selective, leading to the exclusive formation of nitrile/imine compounds. Further, it releases hydrogen as the only side product, suggesting the potential application of the developed catalyst system in hydrogen storage.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Safety of Dichloro(benzene)ruthenium(II) dimer, you can also check out more blogs about37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI