A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 114615-82-6, Name is Tetrapropylammonium perruthenate, molecular formula is C12H28NO4Ru. In a Article£¬once mentioned of 114615-82-6, Quality Control of: Tetrapropylammonium perruthenate
A double donor-activated Ruthenium(VII) catalyst: Synthesis of enantiomerically pure THF-Diols
“Chemical Equation Presented” Double, double, no toll and trouble: Enantiomerically pure tetrahydrofurans are obtained with high position- and stereoselectivity through a ruthenium(Vll)-catalyzed oxidative cyclization of 5,6dihydroxy alkenes (see scheme TPAP = tetrapropylammonium perruthenate). A dual activation modifies the reactivity and increases the carbophilicity of the transition metal so that an otherwise unusual dioxygenation with perruthenate occurs.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Quality Control of: Tetrapropylammonium perruthenate, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 114615-82-6, in my other articles.
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI