In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.SDS of cas: 32993-05-8
Cyclopentadienylruthenium complexes with sulphur ligands II. A comparative study of the reactivity of Ru(eta-RC5H4)Cl(L)2 (R=H, CH3, CH3CO; L=CO, Ph2PCH2CH2PPh2/2, P(CH2CH2CN)3) towards anionic (S-S) donor ligands
The complexes Ru(eta-RC5H4)Cl(PPh3)2 (R=H, CH3, CH3CO) readily react with the tertiary phosphines Ph2PCH2CH2PPh2 (dppe) and P(CH2CH2CN)3 (tcep) to give Ru(eta-RC5H4)Cl(dppe) and Ru(eta-RC5H4)Cl(tcep)2 (R=H, CH3, CH3CO).The dppe complex with R=CH3 reacts with (S2COR’)- ions to give Ru(eta-CH3C5H4)(S2COR’)(dppe) (R’=Me, Et) involving monodentate coordination of the dithiolate, and with (S2CNR’2)- ions to give Ru(S2CNR’2)2(dppe) (R’=Et).The tcep complexes do not react with the dithiolates under these conditions.The reaction of Ru(eta-C5H5)Cl(CO)2 with KS2COEt has also been studied.
Do you like my blog? If you like, you can also browse other articles about this kind. SDS of cas: 32993-05-8. Thanks for taking the time to read the blog about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI