Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10049-08-8, Name is Ruthenium(III) chloride, name: Ruthenium(III) chloride.
Interaction of ruthenium(III) chloride with bis(3,5-dimethylpyrazol-1-yl) methane oxyanions, potential kappa3 -N,N,O scorpionates
When RuCl3 was set to react with both bis(3,5-dimethylpyrazol-1- yl)acetate (bdmpza) and bis(3,5-dimethylpyrazol-1-yl)methane sulfonate (bdmpzsa) new ruthenium(II) complexes were obtained. The reduction of ruthenium(III) was studied by the NMR Evans method and spectrophotometrically, for 1:1 (Ru:L) molar ratios. Using the Evans method pseudo first-order constants of 2.5¡Á10-3 s-1 (bdmpzsa) and 3.9¡Á10 -3 s-1 (bdmpza) were obtained in DMSO-d6 (2% t-butanol) solutions. Spectrophotometrically the corresponding constants were also calculated: 1.1¡Á10-3 s-1 for bdmpzsa, and 1.6¡Á10-3 s-1, for bdmpza. Both ligands behave as kappa3-N,N,O scorpionates but with a weak oxyanionic coordination to the metal, susceptible to be substituted with NEt3 for a 1:1 molar ratio.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Ruthenium(III) chloride. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI