Can You Really Do Chemisty Experiments About (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride, molecular formula is C31H38Cl2N2ORu. In a Article,once mentioned of 301224-40-8, Recommanded Product: 301224-40-8

Polymerization of a series of acetylenes with a hydroxy functional group was investigated by using modified 2nd generation Grubbs (A) and Grubbs-Hoveyda (B) initiators. Owing to excellent tolerance for polar functional groups, catalysts A and B polymerized 3-butyn-2-ol (1), 2-methyl-3-butyn-2-ol (2) and 3-butyn-1-ol (3). The catalytic activities of catalyst B were greater than those of initiator A for these polymerizations. The steric bulk and the position of hydroxyl group of the monomer had an influence on the rate of polymerization. In order to investigate the role of hydroxyl group of monomers in the polymerization, the reaction between hydroxyacetylenes and the ruthenium complexes were monitored by 1H NMR spectroscopy. The results revealed the formation of new alkylidene species via alpha-insertion. The calculated relative energies of propagating species formed in the reaction of A with monomer 1 suggested the formation of oxygen-chelated species. The structures of resulting polymers were characterized by various methods such as NMR, IR and UV-Vis spectroscopies. The ruthenium initiators gave polymers with different geometric structure of main chain than conventional catalysts.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI