Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery., Quality Control of: Dichloro(benzene)ruthenium(II) dimer
The transmetallation reaction between [(eta6-arene)RuCl2]2 (eta6-arene = C6H6 (benzene) (1); 1-Me-iPr-C6H4 (cymene) (2); 1,2,4,5-Me4-C6H2 (durene) (3); 1,2,3,5-Me4-C6H2 (isodurene) (4)) and the aminoaryl-mercury derivatives Hg{Q-dmba}2 (Q-dmba = 1-{C6H3-3-F-6-CH2NMe2} (a); 1-{C6H3-3-Me-6-CH2NMe2} (b); 1-{C6H2-2,3-OCH2O-6-CH2NMe 2} (c); 1-{C6H2-2,4-(MeO)2-6-CH2NMe 2} (d); 1-{C6H4CH2NMe2} (e)) affords the corresponding C,N-cycloruthenated complexes [(eta6-arene)RuCl{Q-dmba}]. All complexes were characterised by 1H and 13C{1H} NMR. The reaction seems to be governed by steric rather than by electronic factors: an increase in the number of alkyl substituents in the eta6-arene ligand or the presence of bulky groups ortho to Hg in the starting material leads to a significant decrease of the yields of the desired cycloruthenated products.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI