Discovery of (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride

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Related Products of 301224-40-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride

1,2-Bis(2-allylphenyl)ethynes undergo cycloisomerisation reactions in the presence of Cp?Ru(ii) catalysts to produce 2,2?-dimethyl-3H,3?H-1,1?-biindenes. On the other hand, tandem ring-closing metathesis of 1,2-bis(2-allylphenyl)ethynes using the Hoveyda-Grubbs 2nd generation catalyst led to the formation of 2,2?-unsubstituted biindenes. Various symmetrical and unsymmetrical bicyclic dienes were prepared by these ruthenium-based cyclisation methods.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI