Related Products of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.
The dinuclear dipolar borabenzene complexes [(eta5-C 5H5)Fe{mu-(eta5-C5H 4)C2(eta6-BC5H5)}ML]X [ML = Ru(eta6-C6H6), X = Cl (4aCl), PF 6 (4aPF6), B(C6H5)4 (4aBPh4); ML = Rh(eta5-C5Me5), X = Cl (4bCl), PF6 (4bPF6); ML = Ir(eta5-C 5Me5), X = Cl (4cC1), PF6 (4cPF6)] were synthesized by a nucleophilic substitution reaction of the trimethylphosphane adduct of borabenzene (1) with lithium ferrocenylacetylide, subsequent lithium-thallium exchange and coordination of the appropriate ML unit obtained from [Ru(eta6-C6H6)Cl(mu -Cl)]2, [M(eta5-C5Me5)Cl(mu -Cl)]2 (M = Rh, Ir); the formed chloride salts, which are soluble in water, were transformed to the PF6 salts by adding [NH 4][PF6] to the corresponding water solution. BPh 4 salts can be produced, when a methanolic solution of Na[BPh 4] were added to CH2Cl2-solutions of the appropriate PF6 salt. X-ray structure analyses of single crystals of 4aBPh4 and 4bPF6 were successful, illustrating the cation 4a+ in an ideal cis-conformation, whereas 4b+ displays a cis- and trans-conformation. Spectroscopic and cyclic voltammetry studies reveal a small but distinct donor-acceptor interaction between the ferrocenyl donor and the cationic borabenzene complex acceptor which increases in the order 4aPF6 < 4cPF6 < 4bPF6. The nonlinear optical properties of these donor-acceptor complexes were studied by means of hyper-Rayleigh scattering (HRS), resulting in the determination of small values for the first hyperpolarisability beta, which increase in the same order as the donor-acceptor interaction. If you are interested in 37366-09-9, you can contact me at any time and look forward to more communication.Related Products of 37366-09-9
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI