Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 92361-49-4, C46H45ClP2Ru. A document type is Article, introducing its new discovery., Quality Control of: Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
The chloro complexes <(eta5-C5Me5)Ru(norbornadiene)Cl> (2), <(eta5-C5Me5)Ru-(ButNC)2Cl> (3), <(eta5-C5Me5)Ru-(PPh3)(ButNC)Cl> (4) and <(eta5-C5Me5)Ru(PPh3)-(CO)Cl> (5) have been prepared from <(eta5-C5Me5)Ru(PPh3)2Cl (1).Reaction of 3-5 with sodium methoxide gave the corresponding hydrides 7-9.All the chloro complexes 1-5 ionise readily in methanol containing NH4PF6 and a donor ligand to give a range of new cations as hexafluorophosphate salts.Treatment of 1 and 4 with NOBF4 gave the dicationic nitrosyls, <(eta5-C5Me5)Ru(PPh3)2NO>(BF4)2 (12) and <(eta5-C5Me5)Ru(PPh3)ButNC)NO>(BF4)2 (17), respectively.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI