The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Optical activity of α-bromopropionitrile》. Authors are Berry, Kenneth L.; Sturtevant, Julian M..The article about the compound:2-Bromopropanenitrilecas:19481-82-4,SMILESS:CC(Br)C#N).Product Details of 19481-82-4. Through the article, more information about this compound (cas:19481-82-4) is conveyed.
In connection with recent theories of optical rotatory power, l-MeCHBrCN (I) has been prepared by asym. conversion from l-MeCHBrCO2H (II). The rotation of II indicated it to be 67.1% l- and 32.9% d-acid; the I, prepared by dehydration of the amide with P2O5, had [α]D25 -5.25°; on the assumption that no racemization occurred during the synthesis the calculated [α]D25 for I is -15.33°. Efforts will be made to prepare a purer I.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI