So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Duquenne, Celine; Gallagher, Timothy F.; Axten, Jeffrey M. researched the compound: Dirhodium(II) tetrakis(caprolactam)( cas:138984-26-6 ).COA of Formula: C24H40N4O4Rh2.They published the article 《A novel method for the 1,2-carbonyl transposition of pleuromutilins》 about this compound( cas:138984-26-6 ) in Tetrahedron Letters. Keywords: pleuromutilin keto preparation transposition; allylic oxidation reduction keto pleuromutilin preparation. We’ll tell you more about this compound (cas:138984-26-6).
A new and efficient 1,2-carbonyl transposition procedure for the formation of 2-keto pleuromutilin compounds, e.g. I, is described. The synthetic sequence is performed in four steps and 26% overall yield.
From this literature《A novel method for the 1,2-carbonyl transposition of pleuromutilins》,we know some information about this compound(138984-26-6)COA of Formula: C24H40N4O4Rh2, but this is not all information, there are many literatures related to this compound(138984-26-6).
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI