Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 138984-26-6, is researched, SMILESS is C12=O[Rh+2]3(O=C4[N-]5CCCCC4)([N-]6C(CCCCC6)=O7)[N-](CCCCC8)C8=O[Rh+2]357[N-]1CCCCC2, Molecular C24H40N4O4Rh2Journal, Article, Research Support, N.I.H., Extramural, Research Support, U.S. Gov’t, Non-P.H.S., Angewandte Chemie, International Edition called Computationally Guided Stereocontrol of the Combined C-H Functionalization/Cope Rearrangement, Author is Lian, Yajing; Hardcastle, Kenneth I.; Davies, Huw M. L., the main research direction is computationally guided stereocontrol carbon hydrogen functionalization Cope rearrangement crystallog.Application of 138984-26-6.
The synthetic utility of the combined C-H functionalization/Cope rearrangement reaction was greatly expanded by the design of substrates that will react through a boat transition state instead of a chair transition state. This gave the reversed diastereomeric series of products in a highly stereoselective manner. This study demonstrates the value of computational studies, not only to rationalize a new synthetic process, but also to identify opportunities to develop new reactions. The results showcase the synthetic potential of using carbenoid chem. to achieve highly enantioselective C-H functionalization reactions.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI