Related Products of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
Structure, dynamic behavior, and catalytic activity of a novel ruthenium cyclopentadienyl complex with a tridentate P,P,O ligand
Reaction of l,2-bis(bis(o-methoxyphenyl)phosphino)ethane (o-MeO-dppe) with [RuClCp(PPh3)2] (1) at 135 C results in the formation of (eta5-cyclopentadienyl)[1-(bis(o-methoxyphenyl)phosphino-kappaP)- 2-((o-methoxyphenyl)(o-phenolato-kappaO)phosphino-kappaP)ethane]ruthenium(II ) ([RuCp(tappe)]; 3), which constitutes the first example of a ruthenium cyclopentadienyl complex with a tridentate P,P,O ligand. The X-ray structure of 3 has been determined to elucidate its solid-state structure, which shows evidence for a CH/pi interaction. An NMR study corroborates this finding, and temperature-dependent 31P and 1H NMR spectra reveal the dynamic behavior of 3 in solution. Complex 3 shows catalytic activity in the isomerization of allylic alcohols to carbonyl compounds.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI