Discovery of 32993-05-8

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Related Products of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

THE PREPARATION OF <(eta-C5H5)RuCl(PPh3)2> FROM AND PENTA-1,4-DIENE; CARBON-CARBON BOND FORMATION BY DEHYROGENATION

reacts with penta-1,4-diene in CD2Cl2, to give initially <(eta3-C5H9)RuCl(PPh3)2>.Dehydrogenation by an excess of pentadiene produces <(eta5-C5H7)RuCl(PPh3)2>.When acetone is used as the dehydrogenating agent, then the reaction proceeds further to yield <(eta-C5H5)RuCl(PPh3)2>.This known compound was prepared quantitatively by refluxing and penta-1,4-diene in methyl ethyl ketone.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI