15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 15746-57-3, HPLC of Formula: C20H16Cl2N4Ru
Long Range Photoinduced Electron Transfer in a Rigid Polymer
Electron (hole) tunnelling reactions are studied in a rigid polymer medium by following the reductive quenching of a series of Ru(LL)3(2+)* homologues by a series of aromatic amines.Tunnelling distances up to 12 Angstroem (edge to edge) are observed.The experimental data include a determination of the exponential damping factor alpha in the electronic term (Hab).The data are consistent with a weak dependence of alpha on binding energy.Such a weak dependence is more consistent with a superexchange description than with a barrier tunnelling description of electron (hole) transfer.These reactions are shown to be essentially temperature independent between 298 K and 359 K, but are significantly slower at 77 K.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: C20H16Cl2N4Ru. In my other articles, you can also check out more blogs about 15746-57-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI