246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, molecular formula is C46H65Cl2N2PRu, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 246047-72-3, category: ruthenium-catalysts
A variable temperature NMR analysis and resonance assignment of the Grubbs second generation catalyst
The Grubbs second generation catalyst [RuCl2(PCy3)(H2IMes)CHPh] was analysed in solution in order to identify and assign all of the 1H and 13C NMR resonances. This was achieved through utilizing various 2D NMR techniques and by acquiring spectra at a range of different temperatures (?40 to 60 C). These assignments will aid researchers in future NMR studies of catalytic systems that employ the Grubbs catalyst by eliminating the resonances belonging to the catalyst and thus enabling the identification of any intermediates and/or new catalytic species. Restricted conformations and pi-stacking arrangement within the catalyst was also confirmed during this study.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: ruthenium-catalysts. In my other articles, you can also check out more blogs about 246047-72-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI