Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 301224-40-8, C31H38Cl2N2ORu. A document type is Article, introducing its new discovery., Safety of (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride
Total synthesis of (-)-dactylolide
Figure Presented Multiple metals in action: Relying on the prowess of various metal-catalyzed C-O and C-C bond-forming reactions, a concise asymmetric total synthesis of (-)dactylolide has been achieved (see scheme). The formation of a Z-trisubstituted vinylboronate through an Alder-ene reaction and subsequent rhenium-mediated regioselective transposition of an allylic alcohol are the key features of this convergent synthesis.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI