Reference of 172222-30-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 172222-30-9, C43H72Cl2P2Ru. A document type is Article, introducing its new discovery.
Ruthenium-catalyzed ring-closing metathesis on alkene-tethered Fischer carbene complexes
Alkene-terminated tethers have been assembled around a Fischer carbene moiety by C-alkylation of the alpha-carbon or N-alkylation of amino carbene complexes by a phase-transfer catalyzed procedure developed in this laboratory. Small or medium-sized, pendant, fused or spirocyclic rings have then been formed by ring-closing metathesis involving such substrates in good to excellent yields. By engaging one of the allyl tethers of a diallylamino group as a ligand for the metal center, it is possible to dictate the direction of cyclization by metathesis.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI