Synthetic Route of 15746-57-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.
In this paper, we describe the enantiospecific synthesis and the complete characterization of the two hexacoordinated ruthenium(II) monocations [Ru(bpy)2ppy]+ and [Ru(bpy)2quo]+ (bpy = 2,2?-bipyridine, ppy = phenylpyridine-H+, quo = 8-hydroxyquinolate) in their enantiomeric Delta and Lambda forms. The corresponding enantiomeric excesses (ee’s) are determined by 1H NMR using pure Delta-Trisphat (tris(tetrachlorobenzenedialato)phosphate(V) anion) as a chiral 1H NMR shift reagent. A complete 1H and 13C NMR study has been carried out on rac-[Ru(bpy)2ppy]PF6 and rac-[Ru(bpy)2quo]PF6. Additionally, the X-ray molecular structure of rac-[Ru(bpy)2quo]PF6 is reported; this latter species crystallizes in the monoclinic C2/c space group (a = 22.079 A, b = 16.874 A, c = 17.533 A, alpha = 90, beta = 109.08, gamma = 90).
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI