Application of 246047-72-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium
New ruthenium olefin metathesis initiators bearing sulfoxide moieties are described. The complexes were synthesized by the reaction of indenylidene ruthenium complexes Ind-II and Ind-II’?with different (2-vinyl)phenyl sulfoxides. These compounds show no catalytic activity at room temperature, but exhibit increased activity at elevated temperature. Preliminary studies on the influence of electronic and steric factors on the catalytic activity are presented.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI