Top Picks: new discover of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery., HPLC of Formula: C41H35ClP2Ru

The cyano and isonitrilo bridged di- and tri-nuclear ruthenium(II) complexes of the types, +Y-, Y and <(L-L)2Ru2>Y2 have been prepared.They have been characterised by elemental analyses, spectral (IR, 1H NMR and electronic) and redox data.The redox and the spectral properties of the <(L-L)2RII> moiety have been rationalised in terms of the competitive ?-back bonding by the second RuII ion centered at +.The (L-L)2ClRuII group in isonitrile bridged complexes is more easily oxidised than that in the corresponding acetonitrile analogue which accords with the spectral behaviour of the complexes.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI