246047-72-3, An article , which mentions 246047-72-3, molecular formula is C46H65Cl2N2PRu. The compound – (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium played an important role in people’s production and life.
Stabilization of (trialkylphosphine)ruthenium alkylidene metathesis catalysts using phosphine exchange
The second-generation Grubbs analogues (H2IMes)-RuCl 2(=CHPh)(PR3) (R = Me, Bu) were essentially metathesisinactive and air-stable at room temperature but exhibited first-order metathesis with ethyl vinyl ether at elevated temperature. The PMe3 complex underwent second-order ligand exchange with PBu3, indicating different coordination mechanisms (dissociative vs associative) in the two reactions.
If you are interested in 246047-72-3, you can contact me at any time and look forward to more communication.246047-72-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI