Category: 114615-82-6

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.114615-82-6, Name is Tetrapropylammonium perruthenate, molecular formula is C12H28NO4Ru. In a Patent，once mentioned of 114615-82-6, Recommanded Product: Tetrapropylammonium perruthenate

Substituted pydrido[1,2-a]pyrazines of general formula I wherein Ar and Ar 1 represent various carbocyclic and heterocyclic aromatic rings; A represents O, S, SO, SO 2, C=O, CHOH, or–(CR. sup.3 R. sup.4) and n is 0-2 as well as precursors thereto are ligands for dopamine receptor subtypes within the body and are therefore useful in the treatment of disorders of the dopamine system. STR1

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Compounds, tautomers and pharmaceutically acceptable salts of the compounds are disclosed, wherein the compounds have the structure of Formula I, as defined in the specification. Corresponding pharmaceutical compositions, methods of treatment, methods of synthesis, and intermediates are also disclosed.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Anti-inflammatory 4-substituted 2-furanones are made from intermediates having the formulas: STR1 in which R1, R2 and R3 independently are n-alkyl of 1 to 6 carbons, or branched chain alkyl of 1 to 6 carbons; X is H, OH, NH2, I or Br; R4 is H, alkyl of 1-20 carbons, phenyl[C1 -C20 alkyl], naphthyl[C1 -C20 alkyl], CH2 OH, CH2 NH2, CH2 CH2 OH, CH2 –CHO, CH2 –COOH or CH2 –COOR5, and R5 is alkyl of 1 to 6 carbons, with the proviso that when X is hydrogen then R4 is selected from the group consisting of CH2 OH, CH2 NH2, CH2 CH2 OH, CH2 –CHO, or CH2 –COOR5 ; STR2 in which R1, R2 and R3 independently are n-alkyl of 1 to 6 carbons, or branched chain alkyl or 1 to 6 carbons, and R5 is alkyl or 1 to 6 carbons; STR3 in which R1, R2 and R3 independently are n-alkyl of 1 to 6 carbons, or branched chain alkyl of 1 to 6 carbons, and R6 is phenyl, or alkyl of 1 to 6 carbons, and STR4 in which R1, R2 and R3 independently are n-alkyl of 1 to 6 carbons, or branched chain alkyl of 1 to 6 carbons.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Compounds of the formula STR1Where the variables are defined as in the specification, are selective agonists of RXR retinoid receptors.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The present invention provides a process for the preparation of pesticidal fluoroolefin compounds having the structural formula I STR1 The present invention also provides intermediate compounds which are utilized in the process of this invention.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 114615-82-6, Name is Tetrapropylammonium perruthenate, molecular formula is C12H28NO4Ru. In a Patent，once mentioned of 114615-82-6, Product Details of 114615-82-6

Oligomeric procyanidins containing 4alpha-linked epicatechin units are rare in nature and have hitherto not been accessible through stereoselective synthesis. Provided herein is the preparation of the prototypical dimer, epicatechin-4alpha,8-epicatechin, by reaction of the protected 4-ketones with aryllithium reagents derived by halogen/metal exchange from the aryl bromides. Removal of the 4-hydroxyl group from the resulting tertiary benzylic alcohols is effected by tri-n-butyltin hydride and trifluoroacetic acid in a completely stereoselective manner, resulting in hydride delivery exclusively from the beta face.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The present invention is directed to pyrrolidine compounds of the formula 1: (wherein R 1, R 2, R 3, R 4, R 5, R 6 and n are defined herein) which are useful as modulators of chemokine receptor activity. In particular, these compounds are useful as modulators of the chemokine receptors CCR-5 and/or CCR-3.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Reference of 114615-82-6, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 114615-82-6, Name is Tetrapropylammonium perruthenate, molecular formula is C12H28NO4Ru. In a Review，once mentioned of 114615-82-6

The current review represents a systematic survey of the use of 2- and 3-carenes in the synthesis of chiral non-racemic organic compounds containing a 2,2-dimethyl-1,3-disubstituted cyclopropane fragment. The synthetic approaches to the cyclopropane derivatives are classified on the basis of the retention of their parent carane bicyclic skeleton in the final product or cleavage of the six-membered ring along the synthetic route.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The present application describes modulators of CCR3 of formula (I): or pharmaceutically acceptable salt forms thereof, useful for the prevention of asthma and other allergic diseases.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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(R)-all-trans-3-hydroxyretinal 1, (S)-all-trans-4-hydroxyretinal 3 and (R)-all-trans-4-hydroxyretinal 5 have been synthesized stereoselectively by Horner-Wadsworth-Emmons and Stille cross-coupling as bond-forming reactions. The CBS method of ketone reduction was used in the enantioface-differentiation step to provide the precursors for the synthesis of the 4-hydroxyretinal enantiomers. The kinetic constants of Xenopus laevis ADH8 with these retinoids have been determined. The Royal Society of Chemistry 2006.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI