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Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 20759-14-2, Name is Ruthenium(III) chloride hydrate, COA of Formula: Cl3H2ORu.

Extraction of ruthenium(III) by bisacylated triethylenetetramine from hydrochloric acid solutions is studied. Ruthenium(III) is extracted by the inner-sphere substitution (solvation-type) mechanism. The donor atoms of the secondary amine nitrogen atom of the extractant enter the inner sphere of the ruthenium(III) ion to form a donor-acceptor bond. The composition of the extracted compound is suggested on the basis of electronic, 1H NMR, and IR spectroscopy and element analysis. Copyright

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The extraction of ruthenium(II) by petroleum sulfoxides (PSOs) from hydrochloric acid solutions has been studied. The extraction of ruthenium(III) by PSOs is implemented by the coordination mechanism with the incorporation of the sulfoxide oxygen atom of the extractant into the inner coordination sphere of the ruthenium(III) ion. The composition of the extraction compound is suggested using electronic, 1H NMR, and IR spectroscopy, the slope method, and elemental analysis. Nauka/Interperiodica 2007.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Benzaldehyde was successfully reduced by catalytic transfer hydrogenation in glycerol using several ruthenium based complexes and bases. Glycerol was employed as a green solvent and hydrogen source, and it allowed for easy product separation and catalyst recycling and enabled the use of a microwave-assisted reaction.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Three new complexes with ligands belong to the fluoroquinolone class having the general formula [RuL2Cl2]Cl nH2O ((1) L: norfloxacin (nf), n = 4; (2) L: ciprofloxacin (cp), n = 3; (3) L: enrofloxacin (enro), n = 5) were synthesized and characterized by chemical analysis UV-Vis and IR spectroscopy. In all complexes fluoroquinolone derivative acts as bidentate chelate ligand. The thermal behavior steps were investigated in synthetic air flow. The thermal transformations are complex processes according to TG and DTG curves including dehydration, quinolone derivative degradation, as well as RuCl3 conversion in RuO2.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The complexes RuCl3(CTZ)3·2CH3OH (1) and RuCl3(KTZ)2(H2O)·2H2O (2) were prepared by reaction of RuCl3·3H2O with CTZ and KTZ, respectively, while RuCl2(KTZ)2 (4) was prepared by reaction of RuCl2(CH3CN)4 with KTZ (CTZ = 1-[(2-chlorophenyl)diphenylmethyl-1H-imidazole, and KTZ = cis-1-acetyl-4-[4-[[2-(2,4-dichlorophenyl)-2-(1H-imidazol-1-ylmethyl)-1,3-dio xolan-4-yl]methoxy]phenyl]piperazine. All the complexes were characterized by NMR spectroscopy and for the paramagnetic species EPR spectroscopy was also employed. The new compounds were tested for in vitro activity against cultures of epimastigotes of Trypanosoma cruzi, the causative agent of Chagas disease, and compared with RuCl2(CTZ)2 (3) (reported previously) in order to establish some structure-activity correlations. At concentrations of 10-6 M (DMSO), all the complexes showed higher activity than the parental organic drug against the epimastigote form of the parasite, and Ru(II) complexes seem to be more active than their Ru(III) counterparts for a given nitrogen-donor ligand.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 20759-14-2, Name is Ruthenium(III) chloride hydrate, molecular formula is Cl3H2ORu. In a Article,once mentioned of 20759-14-2, Recommanded Product: 20759-14-2

Platinum electrocatalysts for fuel cells based on individual oxides Pt/SnO2 and Pt/TiO2 and their solid solutions Pt/Ti 1-xMxO2 (M = Ru, Nb) and Pt/Sn 1-xM’xO2-delta (M’ = Sb, Ru) were prepared. The influence of the composition of the oxide supports on the activity of the supported platinum catalysts in electrooxidation of methanol and hydrogen in the presence of CO was studied. The prepared platinum catalysts supported on solid solutions of tin dioxide Sn1-xMxO2-delta(M = Sb, Ru; x = 0.4-0.9) and Ti1-xMxO2 (M = Ru, Nb; x = 0.7) exhibited higher tolerance to CO poisoning and higher activities for methanol electrooxidation than commercial Pt,Ru catalysts on carbon support. The use of the proposed oxide supported catalysts in hydrogen and direct methanol fuel cells improved their performances in comparison with that for the fuel cells with traditional Pt,Ru catalysts on carbon support.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Osmium(IV) dithioether complexes have been prepared from the ligands and sodium hexachloro-osmate(IV); (L’=MeS(CH2)2SMe or MeSCH=CHSMe) are formed from K2.Iridium(III) anions, , cis and trans-, , and 2, are oxidized by chlorine to the corresponding iridium(IV) complexes.Halogen oxidation of produces (X = Cl or Br) and two unstable complexes .Attempts to prepare thioether complexes of RuIV, RhIV, PdIV, CoIII and NiIII have been unsuccessful .The isolated complexes have been characterized by i.r. and electronic spectroscopy, and where appropriate magnetic measurements and 1H n.m.r. spectroscopy.Variable-temperature 1H n.m.r. spectra show that inversion at sulphur co-ordinated to PtIV is more difficult than in the platinum(II) analogues.Thermal decomposition of (X = Cl,Br, or I) involves both dehalogenation and dealkylation.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Spiro compounds

Spiro compounds of the general formula (I): whereinAr1 represents an optionally substituted aryl or heteroaryl;n represents 0 or 1;T, U, V and W each represent a nitrogen atom or an optionally substituted methine group, wherein at least two of which represent said methine group;X represents nitrogen;Y represents an optionally substituted imino or oxygen atom, which exhibit neuropeptide Y receptor (NPY) antagonistic activities and are useful as agents for the treatment of various diseases related to NPY, for example, cardiovascular disorders, central nervous system disorders, metobolic diseases and the like.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 20759-14-2, Name is Ruthenium(III) chloride hydrate, molecular formula is Cl3H2ORu. In a Article£¬once mentioned of 20759-14-2, Quality Control of: Ruthenium(III) chloride hydrate

METAL COMPLEXES OF SALICYLALDEHYDETHIOUREA, III

Complexes of Pt(IV), Pd(II), Ir(IV), Ru(III), Rh(III), Cu(II), Cd(II), Hg(II), Mn(II) and dioxouranium(VI) with a new Schiff-base, salicylaldehydethiourea, have been synthesized and characterized.The ligand is a 1:1 molar condensation product of salicylaldehyde and thiourea, which on interaction with metal ions gives monoligand type complexes of the formula M(SaTu)Cl(x-1) yH2O, where M = central metal atom; x = 4 for Pt and Ir, 3 for Ru and Rh and 2 for other metals; y = 2 for Ru and Rh complexes, otherwise its value remains unity.The composition, mode of coordination, geometry and thermal behaviour of the chelates have been studied on the basis of elemental analysis, molar conductance, IR and electronic spectra, magnetic moments, TGA and DTA.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Extraction of rutheniumd(III) by bis(butylthioethyl)amine from hydrochloric acid solutions

A polyfunctional sulfur- and nitrogen-containing reagent, bis(butylthioethyl) amine (L), was used as an extradant of ruthenium(III). Optimum conditions for the extraction of ruthenium(III) were determined. It was found that an ion-exchange mechanism of ruthenium(III) extraction took place in the extraction system at a phase contact time of 10 min or shorter. As the phase contact time was longer than 10 min, the extraction took place by a solvation mechanism as inner-sphere substitution with the formation of neutral coordinatively solvated complexes. The composition of the extracted compounds was suggested based on electronic absorption, 1H NMR, and IR spectroscopy and elemental analysis. Copyright

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI