Category: ruthenium-catalysts

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about [Cu15(PPh3)6(PET)13]2+: a Copper Nanocluster with Crystallization Enhanced Photoluminescence.Name: Copper(I) tetra(acetonitrile) tetrafluoroborate.

Due to their atomically precise structure, photoluminescent copper nanoclusters (Cu NCs) have emerged as promising materials in both fundamental studies and technol. applications, such as bio-imaging, cell labeling, phototherapy, and photo-activated catalysis. In this work, a facile strategy is reported for the synthesis of a novel Cu NCs coprotected by thiolate and phosphine ligands, formulated as [Cu15(PPh3)6(PET)13]2+, which exhibits bright emission in the near-IR (NIR) region (≈720 nm) and crystallization-induced emission enhancement (CIEE) phenomenon. Single crystal x-ray crystallog. shows that the NC possesses an extraordinary distorted trigonal antiprismatic Cu6 core and a, unique among metal clusters, “”tri-blade fan””-like structure. An in-depth structural investigation of the ligand shell combined with d. functional theory calculations reveal that the extended C-H···π and π-π intermol. ligand interactions significantly restrict the intramol. rotations and vibrations and, thus, are a major reason for the CIEE phenomena. This study provides a strategy for the controllable synthesis of structurally defined Cu NCs with NIR luminescence, which enables essential insights into the origins of their optical properties.

From this literature《[Cu15(PPh3)6(PET)13]2+: a Copper Nanocluster with Crystallization Enhanced Photoluminescence》,we know some information about this compound(15418-29-8)Name: Copper(I) tetra(acetonitrile) tetrafluoroborate, but this is not all information, there are many literatures related to this compound(15418-29-8).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Copper-Catalyzed Late-Stage Benzylic C(sp3)-H Trifluoromethylation, the main research direction is benzylic trifluoromethylation copper catalyst selective.Safety of Copper(I) tetra(acetonitrile) tetrafluoroborate.

The copper-catalyzed benzylic C(sp3)-H trifluoromethylation was described. With Cu(I) or Cu(II) as the catalyst, (bpy)Zn(CF3)2 (bpy = 2,2′-bipyridine) as the CF3 source, and NFSI (or Selectfluor) as the oxidant, site-selective benzylic C(sp3)-H trifluoromethylation was successfully implemented in high efficiency under mild conditions. The protocol not only exhibits broad substrate scope and wide functional-group compatibility but also allows efficient late-stage C(sp3)-H trifluoromethylation of natural products e.g., I or drug derivatives e.g., II.

From this literature《Copper-Catalyzed Late-Stage Benzylic C(sp3)-H Trifluoromethylation》,we know some information about this compound(15418-29-8)Safety of Copper(I) tetra(acetonitrile) tetrafluoroborate, but this is not all information, there are many literatures related to this compound(15418-29-8).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Reference of 2-Chloro-6-nitrobenzo[d]thiazole. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2-Chloro-6-nitrobenzo[d]thiazole, is researched, Molecular C7H3ClN2O2S, CAS is 2407-11-6, about A DBU-diheteroaryl halide adduct as the fastest current N-diheteroarylating agent. Author is Verma, Sanjeev K.; Acharya, B. N.; Ghorpade, Ramarao; Pratap, Ajay; Kaushik, M. P..

An unexpected diazabicyclo[5.4.0]undec-7-ene (DBU) catalyzed rate enhancement of N-arylation of amines with diheteroaryl halides was reported. DBU was found to activate the Ar-Cl bond of a diheteroaryl halide, forming a green colored adduct under neat conditions. The activated green colored adduct was used for the arylation of amines under neat conditions and was found to be the fastest diheteroarylating agent reported to date.

From this literature《A DBU-diheteroaryl halide adduct as the fastest current N-diheteroarylating agent》,we know some information about this compound(2407-11-6)Reference of 2-Chloro-6-nitrobenzo[d]thiazole, but this is not all information, there are many literatures related to this compound(2407-11-6).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Electric Literature of C7H5NO. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 1,2-Benzisoxazole, is researched, Molecular C7H5NO, CAS is 271-95-4, about Gallium(III) triflate-catalyzed dehydration of aldoximes. Author is Yan, Ping; Batamack, Patrice; Prakash, G. K. Surya; Olah, George A..

Gallium triflate catalyzed dehydration of aldoximes to nitriles is described in good to excellent yields. Good catalytic and dehydrating capabilities of gallium triflate are demonstrated through this dehydration reaction.

From this literature《Gallium(III) triflate-catalyzed dehydration of aldoximes》,we know some information about this compound(271-95-4)Electric Literature of C7H5NO, but this is not all information, there are many literatures related to this compound(271-95-4).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Ring openings with benz-α,β-isoöxazoles. II》. Authors are Lindemann, Hans; Cissee, Hans.The article about the compound:1,2-Benzisoxazolecas:271-95-4,SMILESS:C12=CC=CC=C1ON=C2).Name: 1,2-Benzisoxazole. Through the article, more information about this compound (cas:271-95-4) is conveyed.

cf. C. A. 23, 2973. Me 6-nitroindoxazene-3-carboxylate is reduced by SnCl2 and HCl to the 6-NH2 derivative, yellow, m. 206° (Ac derivative, m. 210°; di-Ac derivative, m. 130°), which by hydrolysis with H2SO4 gives 6-aminoindoxazene-3-carboxylic acid (I), decomposes 160° with the formation of 4,2-H2N(HO)C6H3CN, m. 182° (Ac derivative, decomposes 260-80°). The Et ester of I, m. 147° (Ac derivative, m. 186-7°), with N2H4.H2O gives the hydrazide, yellow, m. 218°, of 6-acetamidoindoxazene-3-carboxylic acid, transformed by HNO2 into the corresponding aside, m. 155° (decomposition); boiling the latter with the appropriate alc. gives the Pr, Bu and iso-Am esters of 6-acetamidoindoxazene-3-carbamic acid, m. 205, 248 and 215° (decomposition), resp. Boiling the azide with dilute AcOH gives 3-amino-6-acetamidoindoxazene, m. 222° (di-Ac derivative, m. 256°; this by warming with 2 N NaOH passes into 3-o-hydroxy-p-acetamidophenyl-5-methyl-1,2,4,-oxdiazole, m. 210°, also obtained by reducing with SnCl2 and HCl the analogous nitrooxdiazole), and either from the hydrolysis of this compound with dilute H2SO4, or by reduction of 6-nirto-3-aminoindoxazine with SnCl2 3,6-diamidoindoxazene, m. 141°, was obtained. 3-Amino-6-acetamidoindoxazene and HNO2 give the 3-HO derivative, m. 160-5° (decomposition); heating with HCO2H gives 2-hydroxy-4-acetamidobenzohydroxamic acid, m. 218°. The last 2 compounds, warmed with EtCO2H or (EtCO)2O, resp., give 2-hydroxy-4-acetamidobenzopropionylhydroxamic acid, m. 194°, which gives with 2 N NaOH 6-acetamido-2-benzoxazolone, m. 320°. Me 6-chloroindoxazene-3-carboxylate, m. 124°, from the NH2 derivative through the Sandmeyer reaction, with 2 N NaOH gives, on long standing, the free acid, decomposes 171°, with remelting above 300°. Either the acid or ester, boiled with 2 N NaOH, gives 4-chloro-2-hydroxybenzonitrile, m. 155° and forming at 180-200° a cyaphenin derivative The above ester with N2H4 in EtOH gives the hydrazide of 6-chloroindoxazene-3-carboxylic acid, decomposes 192°; HNO2 transforms this into the corresponding aside, m. 142° (decomposition), which in turn is converted by warning with AcOH into bis-[6-chloro-3-indoxazenyl]urea, m. 260°, while boiling Ac2O gives 6-chloro-3-acetamidoindoxazene, m. 186° (the free amine m. 135°), transformed by warming with 2 N NaOH into 3-o-hydroxy-p-chlorophenyl-5-methyl-1,2,4-oxdiazole, m. 79°. Me indoxazene-3-carboxylate, m. 69°; free acid, m. 140-1°; hydrazide, m. 143°; azide, m. 95°; sym-bis-3-indoxazenylurea, m. 244°; 3-aminoindoxazene, m. 110° (Ac derivative, m. 155-6°).

From this literature《Ring openings with benz-α,β-isoöxazoles. II》,we know some information about this compound(271-95-4)Name: 1,2-Benzisoxazole, but this is not all information, there are many literatures related to this compound(271-95-4).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Aydogan, Akin; Bangle, Rachel E.; De Kreijger, Simon; Dickenson, John C.; Singleton, Michael L.; Cauet, Emilie; Cadranel, Alejandro; Meyer, Gerald J.; Elias, Benjamin; Sampaio, Renato N.; Troian-Gautier, Ludovic researched the compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)( cas:60804-74-2 ).Recommanded Product: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate).They published the article 《Mechanistic investigation of a visible light mediated dehalogenation/cyclization reaction using iron(III), iridium(III) and ruthenium(II) photosensitizers》 about this compound( cas:60804-74-2 ) in Catalysis Science & Technology. Keywords: bromopentenyl malonate preparation iridium ruthenium dehalogenation cyclization mechanism. We’ll tell you more about this compound (cas:60804-74-2).

The mechanism of a visible light-driven dehalogenation/cyclization reaction was investigated using ruthenium(II), iridium(III) and iron(III) photosensitizers by means of steady-state photoluminescence, time-resolved IR spectroscopy, and nanosecond/fs transient absorption spectroscopy. The nature of the photosensitizer was found to influence the product distribution such that the dehalogenated, non-cyclized products were only detected for the iron photosensitizer. Strikingly, with the iron photosensitizer, large catalytic yields required a low dielec. solvent such as dichloromethane, consistent with a previous publication. This low dielec. solvent allowed ultrafast charge-separation to outperform geminate charge recombination and improved cage escape efficiency. Further, the identification of reaction mechanisms unique to the iron, ruthenium, and iridium photosensitizer represents progress towards the long-sought goal of utilizing earth-abundant, first-row transition metals for emerging energy and environmental applications.

From this literature《Mechanistic investigation of a visible light mediated dehalogenation/cyclization reaction using iron(III), iridium(III) and ruthenium(II) photosensitizers》,we know some information about this compound(60804-74-2)Recommanded Product: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), but this is not all information, there are many literatures related to this compound(60804-74-2).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

HPLC of Formula: 60804-74-2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Coupling an organic photosensitizer and an inorganic framework into a single-phase material that shows visible-light photocurrent response.

By using a photosensitizer [Ru(bpy)3]2+ as a template, a rare example of a three-dimensional Sn-Se type anionic framework, formulated as {Ru(bpy)3@[Sn4Se9]}n1 (bpy = 2,2′-bipyridine), has been synthesized, and shows evident photocurrent response in the visible light region and related semiconducting behavior.

From this literature《Coupling an organic photosensitizer and an inorganic framework into a single-phase material that shows visible-light photocurrent response》,we know some information about this compound(60804-74-2)HPLC of Formula: 60804-74-2, but this is not all information, there are many literatures related to this compound(60804-74-2).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Two new Cu(II) complexes based on 5-fluorouracil-1-yl acetic acid and N-donor ligands: Investigation of their interaction with DNA and anticancer activity, published in 2022-01-31, which mentions a compound: 15418-29-8, mainly applied to copper fluorouracilyl acetate diimine complex preparation DNA interaction; antitumor activity copper fluorouracilyl acetate diimine complex; crystal structure copper fluorouracilyl acetate diimine complex, Application In Synthesis of Copper(I) tetra(acetonitrile) tetrafluoroborate.

Two new Cu(II) complexes [Cu(bpy)2L1] BF4·CH3OH (Z3) and [Cu (phen)2L1] BF4·H2O (Z = 9), L1 = 5-Fluorouracil-1-yl Acetic Acid, were synthesized based on 5-Fluorouracil-1-yl Acetic Acid and 2,2′-Bipyridine or 1,10-phenanthroline ligands and their anticancer activity toward human cancer cell lines studied. The complexes were characterized by IR spectra, elemental anal., and x-ray crystallog. The interaction of the complexes with CT-DNA was studied by UV-visible absorption and fluorescence spectroscopies, and cyclic voltammetry; cell viability (%) was studied using the absorbance amount of the samples. The interaction mode of the complexes with DNA is electrostatic, and the complexes displayed good anticancer activity against HCT 116 (human colorectal cancer cells) and MDA-MB-231 (MD Anderson-metastatic breast) cell lines with best IC50 amount of 11.31 ± 0.74μM for Z = 9. The nature of the nitrogen-donor ligand is very effective in the anticancer activity of the complexes.

There is still a lot of research devoted to this compound(SMILES：[Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-])Application In Synthesis of Copper(I) tetra(acetonitrile) tetrafluoroborate, and with the development of science, more effects of this compound(15418-29-8) can be discovered.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Antituberculous compounds. II. 2-(Benzylidenehydrazino)benzothiazoles》. Authors are Katz, Leon.The article about the compound:2-Chloro-6-nitrobenzo[d]thiazolecas:2407-11-6,SMILESS:O=[N+](C1=CC=C2N=C(Cl)SC2=C1)[O-]).Quality Control of 2-Chloro-6-nitrobenzo[d]thiazole. Through the article, more information about this compound (cas:2407-11-6) is conveyed.

cf. C.A. 46, 933g. 2-Chlorobenzothiazole (I) (170 g.) added during 1 hr. to 300 g. gently refluxing 85% N2H4.H2O (5.1 moles), and the slurry refluxed 15 min., cooled, and filtered yielded 150.6 g. 2-hydrazinobenzothiazole (II), m. 197-9° (all m.ps. uncorrected). p-H2NC6H4CHO (0.075 mole) and 30 g. AcOH heated to 100°, 45 g. succinic anhydride added, the mixture held 3.5 hrs. at 95-100°, diluted with 150 cc. AcOH, let cool overnight, filtered, the dried, powd. cake in 300 cc. water containing 50 cc. concentrated NH4OH stirred 1 hr., 20 g. Supercel added, the mixture filtered, the filtrate acidified with 6 N HCl, and the precipitate filtered off and washed with 500 cc. water yielded 12.5 g. p-(succinylamino)benzaldehyde, HO2CCH2CH2CONHC6H4CHO (III), pale yellow cubes from HCONH2, m. 231-2.5°. p-AcNHC6H4CHO (13.5 g.) added to 150 cc. boiling AcOH and 16.9 g. II, and the slurry stirred 10 min., cooled, filtered, and washed with 300 cc. MeOH yielded 19.5 g. white solid (3.4 g. more from the filtrate), m. 291-3° (from AcOH) (also given as 294-6° from HCONH2, compound 4 below). The preceding method was used for compounds 1-7 below. I (101 g.) added dropwise during 30 min. to 800 g. concentrated H2SO4 at 10-17°, 66 g. powd. KNO3 added portionwise during 1 hr. to the solution cooled to 12° (temperature not to exceed 18°), the solution stirred 15 min., warmed to 25° 30 min., and, after the temperature had risen to 40°, poured into 4 l. ice and water, 6 l. water added, and the solid filtered off yielded 122 g. 2-chloro-6-nitrobenzothiazole (IV), m. 190-1° (from EtOH). N2H4.H2O (300 g.), preheated to 80°, added to 2 l. refluxing EtOH containing 57.0 g. IV, and the mixture stirred 15 min., filtered hot, and washed with 500 cc. EtOH yielded 48.2 g. 6-nitro-2-hydrazinobenzothiazole (V), m. 264-6° (decomposition) (from HCONMe2). Compounds 8-14 below were prepared by the following method: p-HOC6H4CHO (15.0 g.) added to 21.0 g. V and 150 cc. dioxane in 500 cc. boiling AcOH, and the solution held 15 min. at 105-7°, cooled to room temperature overnight, filtered, and washed with 250 cc. MeOH yielded 18.1 g. compound 8; the filtrate, diluted to 1.33 l. with water, yielded 4.9 g. more. III (8.8 g.) in 50 cc. boiling water containing 3 cc. concentrated NH4OH added to 350 cc. boiling AcOH containing 11.0 g. V and 10 cc. HCONH2, and the mixture cooled to room temperature, diluted with 300 cc. MeOH, and filtered yielded 14.1 g. compound 13, m. 319-21°. IV (21.0 g.) added portionwise during 1 hr. to 150 cc. EtOH, 10 g. AcOH, 250 cc. water, and 50 g. 100-mesh Fe which had been heated to 80-5° 30 min., the mixture held at 80° 1 hr., 200 cc. EtOH and 10 g. Darco G-60 added, the mixture refluxed 15 min., filtered hot into 250 cc. water, and the filtrate chilled yielded 13.8 g. 6-amino-2-chlorobenzothiazole (VI), m. 155-7°. AcCl (10.8 g.) added dropwise during 20 min. to 18.4 g. VI and 70 cc. pyridine at 10°, and the mixture stirred 30 min. at 0-10°, poured into 800 cc. water, and filtered yielded 21.6 g. 6-Ac derivative (VII), fine white needles from the min. amount of EtOH added to 40 volumes hot water, m. 131-2°. VII (42.5 g.) added quickly to 150 g. boiling N2H4.H2O, the slurry diluted with 125 cc. hot water, boiled 5 min., 150 g. ice added, and the mixture filtered yielded 38.3 g. 6-acetamido-2-hydrazinobenzothiazole (VIII), m. 233-5° (from aqueous MeOH). Compounds 15-20 were prepared by the following method: VIII (3.0 g.) in 100 cc. boiling 25% AcOH treated with 3.0 g. p-HOC6H4CHO, and the mixture stirred 10 min., cooled, and filtered yielded 3.4 g. compound 15, m. 274-7°. VI (10 g.) and 50 g. N2H4.H2O boiled 5 min., cooled to 20°, and filtered yielded 8.6 g. 6-amino-2-hydrazinobenzothiazole, m. 209.5-11° (from iso-PrOH). Pyridine (20 cc.), 1.3 g. VI, and 2.0 g. PhSO2Cl heated to boiling, and the solution cooled and poured into 150 cc. water yielded 2.1 g. 2-chloro-6-(phenylsulfonamido)benzothiazole (IX), m. 176-7.5° (from aqueous EtOH). IX (2.1 g.) and 20 g. N2H4.H2O boiled 5 min., cooled, and neutralized with 6 N H2SO4 yielded 1.7 g. 2-hydrazino-6-(phenylsulfonamido)benzothiazole, pale yellow crystals from PhMe-EtOH, m. 214-16°. For the 2-(benzylidinehydrazino)benzothiazoles (X), the compound number, R, R1, yield (%), m.p. (uncorrected), and recrystallization solvent are: 1, H, OH, 80,253-4.5°, AcOH; 2, H, Ac, 70, 194-5°, iso-PrOH; 3, H, OCH2CO2H, 81, 254-7° dioxane; 4, H, NHAc, 89, 294-6°, HCONH2; 5, H, NMe2, 77, 243-4.5° iso-PrOH; 6, H, NHCOCH2CH2CO2H, 91, 255-7°, AcOH; 7, H, CO2H, 86, 319-20°, HCONH2; 8, NO2, OH, 73, 318-19°, HCONH2; 9, NO2, OMe, 72, 299-300° AcOH; 10, NO2, OCH2CO2H, 68, 280-1.5° HCONH2; 11, NO2, NHAc, 70, 312-13° HCONMe2; 12, NO2, NMe2, 77, 263-5° AcOH; 13, NO2, NHCOCH2CH2CO2H, 81, 326-8°, HCONH2; 14, NO2, CO2H, 69, 331-2° AcOHHCONH2 (3:2); 15, NHAc, OH, 77, 279-81°, 50% aqueous HCONH2; 16, NHAc, OMe, 93, 262-3° HCONH2; 17, NHAc, OCH2CO2H, 84, 296-7° HCONH2; 18, NHAc, NHAc, 89, 292-3°, HCONH2; 19, NHAc, NMe2, 91, 286-7° HCONH2; 20, NHAc, CO2H, 86, 326-7°, AcOH. Compounds 3 and 5 were the most active.

There is still a lot of research devoted to this compound(SMILES：O=[N+](C1=CC=C2N=C(Cl)SC2=C1)[O-])Quality Control of 2-Chloro-6-nitrobenzo[d]thiazole, and with the development of science, more effects of this compound(2407-11-6) can be discovered.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)( cas:60804-74-2 ) is researched.Recommanded Product: 60804-74-2.Dai, Lei; Ye, Song published the article 《Photo/N-Heterocyclic Carbene Co-catalyzed Ring Opening and γ-Alkylation of Cyclopropane Enal》 about this compound( cas:60804-74-2 ) in Organic Letters. Keywords: photochem heterocyclic carbene catalyst ring opening alkylation cyclopropane enal; alkylated unsaturated ester preparation. Let’s learn more about this compound (cas:60804-74-2).

An unprecedented photo/NHC-co-catalyzed ring-opening C-C bond cleavage of cyclopropane enal and the following γ-alkylation with a halogenated compound via radicals were established, affording the corresponding γ-alkylated α,β-unsaturated esters in moderate to good yields.

There is still a lot of research devoted to this compound(SMILES：F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2])Recommanded Product: 60804-74-2, and with the development of science, more effects of this compound(60804-74-2) can be discovered.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI