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COA of Formula: C8H12BCuF4N4. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Heterometallation of Photoluminescent Silver(I) Sulfide Nanoclusters Protected by Octahedral Iridium(III) Thiolates. Author is Goo, Zi Lang; Minami, Katsue; Yoshinari, Nobuto; Konno, Takumi.

The recently-increasing interest in coinage metal clusters stems from their photophys. properties, which are controlled via heterometalation. Herein, the authors report homometallic Ag46IS13 clusters protected by octahedral fac-[Ir(aet)3] (aet = 2-aminoethanethiolate) mols. and their conversion to heterometallic Ag43IM3IS13 (M=Cu, Au) clusters. The reactions of fac-[Ir(aet)3] with Ag+ and penicillamine produced [Ag46S13{Ir(aet)3}14]20+ ([1]20+), where a spherical Ag46IS13 cluster is covered by fac-[Ir(aet)3] octahedra through thiolato bridges. [1]20+ was converted to [Ag43M3S13{Ir(aet)3}14]20+ ([1M]20+) with an Ag43IM3IS13 cluster by treatment with M+, retaining its overall structure. [1]20+ was photoluminescent and had an emission band ∼690 nm that originated from an S-to-Ag charge transfer. While [1Cu]20+ showed an emission band with a slightly higher energy of ∼650 nm and a lower quantum yield, the emission band for [1Au]20+ shifted to a much higher energy of ∼590 nm with an enhanced quantum yield.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Recommanded Product: 15418-29-8. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Thermally regenerative copper nanoslurry flow batteries for heat-to-power conversion with low-grade thermal energy. Author is Maye, Sunny; Girault, Hubert H.; Peljo, Pekka.

Low-grade heat (below 200°C) is available in vast quantities from industry, or from standard roof-top solar thermal collectors. However, the production of elec. power from these heat sources is challenging with existing technologies. Thermally regenerative batteries allow both the conversion and the storage of thermal energy into elec. power, but they suffer from low operation voltages and low output power. Here, we propose a thermally regenerative nanoslurry flow battery based on copper complexation with acetonitrile in non-aqueous solutions operating at voltages above 1 V. The Cu(I) complex can be destabilized by the removal of acetonitrile by distillation, leading to the production of solid copper nanoparticles and Cu(II) in solution, thereby charging the battery. We demonstrate the electricity production at average power densities of 90 W m-2 and peak-power densities up to 150 W m-2, and estimate the theor. efficiency of the full system at 2%. The results demonstrate a proof-of-concept for harvesting and storage of electricity from low-quality heat.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

9/29 News Our Top Choice Compound: Tetrapropylammonium perruthenate

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There are disclosed compounds of formula (I) STR1 and pharmaceutically acceptable salts thereof which are useful as antagonists of GnRH and as such may be useful for the treatment of a variety of sex-hormone related and other conditions in both men and women.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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Disclosed is a synthesis method of chiral tetrahydroquinoline derivatives. According to the present invention, chiral tetrahydroquinoline derivatives having high optical purity can be efficiently synthesized from cinnamyl alcohol derivatives using tetrapropylammonium perruthenate as a catalyst and a chiral catalyst in the presence of oxygen (O_2).COPYRIGHT KIPO 2016

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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CCR3 antagonist leads with IC50 values in the muM range were converted into low nM binding compounds that displayed in vitro inhibition of human eosinophil chemotaxis induced by human eotaxin. In particular, 4-benzylpiperidin-1-yl-n-propylureas and erythro-3-(4-benzyl-2-(alpha-hydroxyalkyl)piperidin-1-yl)-n-propylureas (obtained via Beak reaction of N-BOC-4-benzylpiperidine) exhibited single digit nanomolar IC50 values for CCR3.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The π-electrons of these planar compounds are free to cycle around the circular arrangements of atoms found in the aromatic moieties. This stems from the resonance found in planar ring systems, like benzene, and 114615-82-6!, Related Products of 114615-82-6

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The Ley?Griffith oxidation, which is catalyzed by tetra-n-propylammonium perruthenate (TPAP, nPr4N[RuO4]), is a popular method for not only controlled oxidation of primary alcohols to aldehydes, but also a host of other synthetically useful transformations. While the fundamental reaction mechanism has recently been elucidated, several key hydrogen-bonding interactions between the reagents were implicated but not investigated. Herein the prevalence of H-bonding between the co-oxidant N-methylmorpholine N-oxide (NMO), the alcohol substrate, water and the perruthenate catalyst is established. These observations help to rationalize the importance of drying the reagents and lead to several practical suggestions.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The invention provides compounds of the general formula (I): STR1 or a physiologically acceptable salt, solvate (e.g. hydrate) or a metabolically labile ester thereof. The compounds may be used in the treatment or prophylaxis of hypertension and diseases associated with cognitive disorders.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The development of selective steroidal mineralocorticoid receptor antagonists with improved pharmacological profiles over existing marketed drugs is an attractive goal. Such compounds offer potential for the treatment of hypertension, heart failure and renal disease. With this aim, new spirolactones were prepared exploring substitutions at carbons 6, 7, 9?11, 15?16 and 21. Spirolactones 11 a and 20 were identified with promising biological profiles. Both compounds restored Na+/K+ ratios to physiological levels in an in vivo model.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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The use of compounds of the formula (I), and salts thereof; and pharmaceutically acceptable in vivo cleavable prodrugs of said compound of formula (I); and pharmaceutically acceptable salts of said compound or said prodrugs: STR1wherein:Ring C is phenyl or a carbon linked heteroaryl ring substituted as defmed within;R 1 is an ortho substituent as defined within;n is 1 or 2;A–B is a linking group as defined within;R 2 and R 3 are as defined within;R 4 is hydroxy, hydrogen, halo, amino or methyl; in the manufacture of a medicament for use in the elevation of PDH activity in warm-blooded animals such as humans is described. Pharmaceutical compositions, methods and processes for preparation of compounds of formula (I) are also described.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

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New drugs introduced to the market every year represent privileged structures for particular biological targets. These new chemical entities (NCEs) provide insight into molecular recognition and also serve as leads for designing future new drugs. This annual review covers the synthesis of thirty-seven NCEs that were approved for the first time in 2014 and one drug which was approved in 2013 and was not covered in a previous edition of this review.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI