Tag: M.W:400-500

37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, name: Dichloro(benzene)ruthenium(II) dimer

(Figure Presented) Alkane and arene join together: Various arenes were coupled directly with simple cycloalkanes. The reaction was catalyzed by ruthenium under oxidative conditions to give substituted cycloalkylarenes regioselectively (see scheme).

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.SDS of cas: 15746-57-3

Ruthenium complexes containing pdon (pdon = 1,10-phenanthroline-5,6-dione) were synthesized. Their spectroscopic and electrochemical properties were examined. The molecular structure with [Ru(pdon)(bpy)2](ClO 4)2 ([1](ClO4)2) (bpy = 2,2?-bipyridyl) was determined by single crystal X-ray diffraction. The optically transparent thin-layer electrochemical measurements confirm that the quinone form of [1](ClO4)2 is reduced to the semi-quinone state in acetonitrile (E? = -8 mV). Comparing the model complex, [1](ClO4)2, and metal-free pdon, the positive charge on two carbon atoms of the o-quinone group is bigger than that of metal-free pdon. The assemblies of the complexes were finally examined using ligand substitution.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Application of 37366-09-9, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9

A ruthenium-dioxolene-amine complex, [RuIII(NH 2-L)(Bu2sq)](PF6)2·0.5H 2O (NH2-L = bis(2-pyridylmethyl)-2-aminoethylamine, Bu2sq- = 3,5-di-tert-butylsemiquinonate), was newly prepared. The complex undergoes spontaneous one-electron reduction under basic conditions in MeOH and works as an electrocatalyst in the oxidation of benzyl alcohol to benzaldehyde under electrolysis at +0.4 V (vs SCE).

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 37366-09-9 is helpful to your research., Application of 37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 15746-57-3, C20H16Cl2N4Ru. A document type is Article, introducing its new discovery., COA of Formula: C20H16Cl2N4Ru

The new click-adduct 4,5-di(2-pyridyl)-1,2,3-triazole acts as a doubly-chelating anionic bridging ligand that forms dinuclear ruthenium(ii) complexes which exhibit strong metal-metal interactions. The Royal Society of Chemistry.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Related Products of 15746-57-3, An article , which mentions 15746-57-3, molecular formula is C20H16Cl2N4Ru. The compound – Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II) played an important role in people’s production and life.

Novel redox-active DNA labeling tags with tunable electrochemical potentials are modularly synthesized using (a) bis-substituted Ru2+ or Os2+ precursors (R2bpy)2ML2, (b) substituted 2,4-pentanediones or hydroxamic acids bearing a functionalized linker, and (c) modified nucleotides. DNA polymerase efficiently incorporates the metal-containing nucleotide triphosphate into DNA oligonucleotides. Copyright

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Electric Literature of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.

New series of half-sandwich ruthenium(II) complexes supported by a group of bidentate pyridylpyrazole and pyridylimidazole ligands [(eta6-C6H6)Ru(L2)Cl][PF6] (1), [(eta6-C6H6)Ru(HL3)Cl][PF6] (2), [(eta6-C6H6)Ru(L4)Cl][PF6] (3), and [(eta6-C6H6)Ru(HL5)Cl][PF6] (4) [L2, 2-[3-(4-chlorophenyl)pyrazol-1-ylmethyl]pyridine; HL3, 3-(2-pyridyl)pyrazole; L4, 1-benzyl-[3-(2?-pyridyl)]pyrazole; HL5, 2-(1-imidazol-2-yl)pyridine] are reported. The molecular structures of 1-4 both in the solid state by X-ray crystallography and in solution using 1H NMR spectroscopy have been elucidated. Further, the crystal packing in the complexes is stabilized by C-H?X (X = Cl and pi), N-H?Cl, and pi-pi interactions.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Application of 37366-09-9, An article , which mentions 37366-09-9, molecular formula is C12H12Cl4Ru2. The compound – Dichloro(benzene)ruthenium(II) dimer played an important role in people’s production and life.

The invention discloses a ruthenium complex, with a light-activated antibacterial function, which has the structure I shown : Wherein, R is selected from H or – OCH. 3 ;X. A monovalent anion, representing a balanced charge, which has the ability, to penetrate cell membranes and bacteria, does not possess the ability, to penetrate the nucleus but has a strong lethality on the bacteria under light conditions, to overcome the resistance, of bacteria to traditional chemotherapeutic antibiotics, and the invention also discloses a preparation method and application, of the complex. (by machine translation)

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, COA of Formula: C12H12Cl4Ru2

p53 is a key tumor suppressor gene involved in key cellular processes and implicated in cancer therapy. However, it is inactivated in more than 50% of all cancers due to mutation or overexpression of its negative regulators. This leads to drug resistance and poor chemotherapeutic outcome as most clinical drugs act via a p53-dependent mechanism of action. An attractive strategy to circumvent this resistance would be to identify new anticancer drugs that act via p53-independent mode of action. In the present study, we identified 9 Ru (II)-Arene Schiff-base (RAS) complexes able to induce p53-independent cytotoxicity and discuss structural features that are required for their p53-independent activity. Increasing hydrophobicity led to an increase in cellular accumulation in cells with a corresponding increase in efficacy. We further showed that all nine complexes demonstrated p53-independent activity. This was despite significant differences in their physicochemical properties, suggesting that the iminoquinoline ligand, a common structural feature for all the complexes, is required for the p53-independent activity.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.COA of Formula: C12H12Cl4Ru2, you can also check out more blogs about37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Electric Literature of 15746-57-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)

With the radical 2?,5?-dihydro-4?,5?,5?-trimethyl-spiro-[4,5- diazafluorene-9,2?-imidazol]-1-oxyl L a series of transition metal complexes has been prepared: [ML3](SbF6)2· 4H2O with M2+ = Mn2+ (1), Fe2+ (2), Co2+ (3), Ni2+ (4), Zn2+ (5). Reaction of L with Cu2+ in methanol yielded different products depending on the counterion. In the presence of weakly coordinating anions the Cu(I) complexes [Cu2L3](SbF6)2 · H2O (6), [Cu2L3](OTf)2 · 2MeOH (7) and [Cu2L3](ClO4)2 (8) were formed. Stronger coordinating counter ions gave the complexes CuL2Cl2 · H2O (9), CuL2Br2 · H2O (10) and CuL2(NO3)2 (11). Also the synthesis of [Ag2L3](SbF6)2 · 2H2O (12), Pd(L)Cl2 · H2O (13), Pt(L)Cl2 · H2O (14), Ni(L)Cl2 (15a), Ni(L)Cl2 · 4H2O (15b) and [Ru(bipy)2(L)]Cl2 · 4H2O (16) is reported. The magnetic moments of 1-6 and 10 correspond in the range 200-300 K to those expected for noninteracting spins of the metal ion and the radicals. At low temperatures spin pairing of metal and radical spins is observed for 1-3.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Related Products of 15746-57-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.

The attachment of two polyethylene glycol tails (n = 7, MW = 350) to ruthenium tris(bipyridine) via ester links on the 4,4′-positions of one of the bipyridine ligands yields a highly viscous (eta ? 107 cP) molten salt (abbreviated [Ru(bpy)2(bpy(CO2MePEG350)2)](ClO4)2) that glasses at ca. – 5 C. At room temperature, the ionic conductivity of the melt is sufficiently high that application of 2.4 V across the fingers of a Pt interdigitated electrode array (IDA) coated with the melt leads to the electrolytic development of serial concentration gradient microstructures of Ru(III/II) and Ru(II/I) states. At the intersection of the two concentration gradients, in the interior of the coating, reaction between the Ru(III) and Ru(I) states leads to ECL emission with an efficiency of 0.2% photons/electron. Cooling a concentration gradient-containing film to -20 C under voltage bias, so as to preserve the gradient microstructure, yields a film that has an emission efficiency of 0.1%, a current and light emission response that rapidly changes with the applied voltage bias, and a diode- like current-voltage profile with a ca. 100 rectification ratio.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI