Final Thoughts on Chemistry for (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

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We described the highly efficient synthesis of cis-hydrindenols from 2-allylbicyclo[2.2.2]octenol derivatives using the Diels-Alder adducts of masked o-benzoquinones (MOBs) with suitable dienophiles, as precursors for ring-rearrangement metathesis (RRM). These facile, versatile, and operationally simple transformation strategies produced cis-hydrindenol products with four stereo-centers and a tertiary hydroxyl functional group.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI