9-Sep-2021 News Top Picks: new discover of Dichloro(benzene)ruthenium(II) dimer

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In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.Safety of Dichloro(benzene)ruthenium(II) dimer

Reaction of [RuCl2(eta6-C6H 6)]2 with [10-(CH3)2S-7,8-nido- C2B9H10]- or [9-(CH 3)2S-7,8-nido-C2B9H10] afforded the expected cationic complexes [Ru(eta5-n-(CH 3)2S-7,8-C2B9H10) (eta6-C6H6)]+ (n = 10, (1); 9, (3)), but also the unexpected neutral Ru(eta5-10-HS-7,8-C 2B9H10)(eta6-C6H 6) (2) or Ru(eta5-9-(CH3)S-7,8-C 2B9H10)(eta6-C6H 6) (4) by double and mono demethylation of the (CH3) 2S moiety, respectively.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI